MERRILL LYNCH PENNSYLVANIA MUNICIPAL BOND FUND
N-30D, 1994-09-06
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MERRILL
LYNCH
PENNSYLVANIA
MUNICIPAL
BOND FUND


Annual Report   July 31, 1994


This report is not authorized for use as an offer of sale or a
solicitation of an offer to buy shares of the Fund unless
accompanied or preceded by the Fund's current prospectus. Past
performance results shown in this report should not be considered a
representation of future performance. Investment return and
principal value of shares will fluctuate so that shares, when
redeemed, may be worth more or less than their original cost.

Merrill Lynch Pennsylvania
Municipal Bond Fund
Merrill Lynch Multi-State
Municipal Series Trust
Box 9011
Princeton, New Jersey
08543-9011




TO OUR SHAREHOLDERS

<PAGE>
The expectation of increasing inflationary pressures and higher
interest rates initially heightened investor concerns and increased
financial market volatility during the July quarter. However, as the
quarter progressed, it was the weakness of the US dollar in foreign
exchange markets that dominated the financial news and prolonged
stock and bond market declines. Although the US dollar had
strengthened slightly by July quarter-end, which may have improved
investor confidence in the stock and bond markets, the possibility
of continued tightening by the Federal Reserve Board resurfaced
following Chairman Alan Greenspan's recent congressional testimony.
Nevertheless, as the quarter drew to a close, a lower-than-expected
rate of growth reported for the US economy during the second
calendar quarter allayed investor concerns and led to stock and bond
market rallies.

During the July quarter, the US dollar's weakness relative to other
major currencies reflected the deteriorating US trade deficit and
widening net long-term capital outflows. In 1993, an expanding US
economy and recession in other industrial countries led to a higher
level of imports and weaker export growth, widening the US trade
deficit further. In addition, global investors favored non-US dollar
denominated assets throughout 1993, which has further depressed the
dollar's value. This trend is not improving significantly thus far
in 1994 since foreign inflows into US capital markets continue to
decline, although US investors are investing outside of the United
States to a lesser degree.

Over the longer term, if the economies of the United States' major
trading partners expand (improving the prospects for US export
growth), the outlook for the US dollar is likely to improve. In the
near term, central banks have attempted to reverse the dollar's
decline through currency market intervention. These efforts have met
with limited success thus far, giving rise to the concern that the
Federal Reserve Board will be forced to continue to raise short-term
interest rates to attract investment capital back to the United
States and bolster the dollar's value. However, further interest
rate increases may jeopardize the US economic expansion. Despite
evidence of a moderating trend in the US economy, Federal Reserve
Board Chairman Alan Greenspan indicated in his July Humphrey-Hawkins
testimony that the central bank would prefer to err on the side of
too much monetary tightening rather than too little. In the weeks
ahead, investors will continue to assess economic data and
inflationary trends as they focus on the US dollar in order to gauge
whether further increases in short-term interest rates are imminent.
Continued indications of moderate and sustainable levels of economic
growth would be positive for the US capital markets.
<PAGE>
The Municipal Market
Long-term tax-exempt bond yields ended the July quarter essentially
unchanged. The Bond Buyer Revenue Bond Index rose five basis points
(0.05%) to 6.47%. The Index, however, failed to capture the dramatic
bond rally on July 29, 1994, when municipal bond yields had their
largest one-day decline thus far this year. Responding to reports of
a continued mild inflationary outlook and a potentially weakening
economy, municipal bond yields declined by approximately 10 basis
points. US Treasury bonds displayed a similar pattern over the last
three months, ending with an equally dramatic rally on July 29,
1994. Long-term US Treasury bonds ended the quarter yielding
approximately 7.40%.

The tax-exempt bond market has continued to be very volatile with
yields fluctuating by as much as 15 basis points from week to week.
This continued volatility is largely a reflection of the same lack
of conviction regarding the near-term direction of interest rates
that has prevailed for much of 1994. Throughout this past quarter,
the municipal bond market had been unable to maintain a consensus
regarding either the potential strength of the current economic
recovery or the resultant response by the Federal Reserve Board.
However, a number of economic indicators released in late July began
to suggest that the robust pace of recent economic growth was
slowing. This promoted a more positive market environment,
culminating in the market rally on July 29, 1994.

The municipal bond market's technical position has remained
supportive. Approximately $40 billion in long-term securities were
issued during the three months ended July 31, 1994. This represents
a decline of over 50% versus the July quarter from the previous
year. As discussed in earlier reports, this reduction in new-issue
supply has minimized the selling pressure by larger institutional
investors who fear being unable to purchase sizable amounts of
securities in the future. Such a significant decline in issuance
would normally be expected to trigger a decline in yields as
investors chase a commodity in scarce supply. Investor demand,
however, has also diminished somewhat in recent months as net flows
into long-term municipal bond funds have dramatically slowed or, in
some instances, reversed. Consequently, the supply/demand
relationship within the municipal bond market has remained in
balance, promoting the overall stability in yield levels seen in the
past months.
<PAGE>
With after-tax equivalents in excess of 10%, long-term tax-exempt
bonds continue to represent considerable value relative to other
investment alternatives. We continue to anticipate that municipal
bond yields will decline further in late 1994 and into 1995. The
economic impact of the significant interest rate increases
experienced since early February have yet to be totally realized.
The resultant drag on the economy should provide the foundation for
further interest rate declines. Under such a scenario, current tax-
exempt bond yields may prove to represent considerable value.

Fiscal Year In Review
During the past twelve months, the municipal bond market has been
extremely volatile. As measured by the Bond Buyer Revenue Bond
Index, long-term tax-exempt bond yields ranged from a low of 5.41%
on October 14, 1993 to a high of 6.60% on May 12, 1994. At year-end
July 31, 1994, the Index was near the peak for the period, yielding
6.47%. The change in direction of long-term interest rates occurred
as a result of the US economy heating up during the fourth quarter
of 1993 and generating momentum which carried forward into 1994.
This led the Federal Reserve Board to tighten monetary policy in
February in an attempt to prevent an increase in inflationary
pressures on the economy. In response to the rapidly changing
investment climate, prices of long-term fixed income securities fell
sharply.

Merrill Lynch Pennsylvania Municipal Bond Fund altered its portfolio
strategy during the past twelve months as market psychology changed.
Entering the year fully invested, the Fund took advantage of the
decline in interest rates through the fall of 1993. However, as
evidence of a booming economy emerged early in 1994, we became
cautious on the market. Strategy centered on raising the Fund's cash
reserves to approximately 10% of net assets and restructuring the
portfolio's holdings to include a greater percentage of defensive
bonds. This entailed selling discount coupons and buying higher-
coupon bonds which are priced to call. As a result, we were able to
mute some of the volatility that occurred and, in effect, limit the
decline in total returns of the Fund's Class A and Class B Shares
that the Fund experienced during this very difficult period in 1994.

In Conclusion
We appreciate your ongoing interest in Merrill Lynch Pennsylvania
Municipal Bond Fund, and we look forward to assisting you with your
financial needs in the months and years to come.

Sincerely,




(Arthur Zeikel)
Arthur Zeikel
President
<PAGE>


(Vincent R. Giordano)
Vincent R. Giordano
Vice President and Portfolio Manager

August 25, 1994



PERFORMANCE DATA



None of the past results shown should be considered a representation
of future performance. Investment return and principal value of
Class A and Class B Shares will fluctuate so that shares, when
redeemed, may be worth more or less than their original cost.


Average Annual Total Return--Class A Shares*

                             % Return Without        % Return With
                               Sales Charge          Sales Charge**

Year Ended 6/30/94                +0.36%                 -3.65%
Inception (8/31/90)
through 6/30/94                   +8.65                  +7.50

[FN]
 *Maximum sales charge is 4%.
**Assuming maximum sales charge.

GRAPHIC MATERIAL APPEARS HERE. SEE APPENDIX,
GRAPHIC AND IMAGE MATERIAL: Item 1.


Average Annual Total Return--Class B Shares*

                              % Return                  % Return
                            Without CDSC               With CDSC**

Year Ended 6/30/94                -0.15%                 -3.92%
Inception (8/31/90)
through 6/30/94                   +8.08                  +7.87

[FN]
 *Maximum contingent deferred sales charge is 4% and is reduced
  to 0% after 4 years.
**Assuming payment of applicable contingent deferred sales charge.
<PAGE>
GRAPHIC MATERIAL APPEARS HERE. SEE APPENDIX,
GRAPHIC AND IMAGE MATERIAL: Item 2.


PERFORMANCE DATA (concluded)
<TABLE>
Performance Summary--Class A Shares
<CAPTION>
                         Net Asset Value          Capital Gains
Period Covered        Beginning     Ending         Distributed         Dividends Paid*      % Change**
<C>                      <C>          <C>             <C>                   <C>              <C>
8/31/90--12/31/90        $10.00       $10.05              --                $0.237           + 2.90%
1991                      10.05        10.61              --                 0.678           +12.75
1992                      10.61        10.90          $0.005                 0.660           + 9.31
1993                      10.90        11.65           0.040                 0.638           +13.39
1/1/94--7/31/94           11.65        11.00              --                 0.336           - 2.60
                                                      ------                ------
                                                Total $0.045          Total $2.549

                                                      Cumulative total return as of 7/31/94: +40.06%**

<FN>
 *Figures may include short-term capital gains distributions.
**Figures assume reinvestment of all dividends and capital gains
  distributions at net asset value on the payable date, and do not
  include sales charge; results would be lower if sales charge was
  included.
</TABLE>

<TABLE>
Performance Summary--Class B Shares
<CAPTION>
                         Net Asset Value          Capital Gains
Period Covered        Beginning     Ending         Distributed         Dividends Paid*      % Change**
<C>                      <C>          <C>             <C>                   <C>              <C>
8/31/90--12/31/90        $10.00       $10.05              --                $0.219           + 2.73%
1991                      10.05        10.61              --                 0.626           +12.18
1992                      10.61        10.90          $0.005                 0.605           + 8.76
1993                      10.90        11.65           0.040                 0.580           +12.82
1/1/94--7/31/94           11.65        11.00              --                 0.304           - 2.87
                                                      ------                ------
                                                Total $0.045          Total $2.334

                                                      Cumulative total return as of 7/31/94: +37.33%**
<FN>
 *Figures may include short-term capital gains distributions.
**Figures assume reinvestment of all dividends and capital gains
  distributions at net asset value on the payable date, and do not
  reflect deduction of any sales charge; results would be lower if
  sales charge was deducted.
</TABLE>
<PAGE>
<TABLE>
Recent Performance Results*
<CAPTION>
                                                                                 12 Month     3 Month
                                               7/31/94   4/30/94    7/31/93      % Change     % Change
<S>                                             <C>       <C>        <C>         <C>           <C>
Class A Shares                                  $11.00    $10.89     $11.39      -3.09%(1)     +1.01%
Class B Shares                                   11.00     10.89      11.39      -3.09(1)      +1.01
Class A Shares--Total Return                                                     +2.37(2)      +2.40(3)
Class B Shares--Total Return                                                     +1.86(4)      +2.27(5)
Class A Shares--Standardized 30-day Yield         5.08%
Class B Shares--Standardized 30-day Yield         4.78%

<FN>
  *Investment results shown for the 3-month and 12-month periods are
   before the deduction of any sales charges.
(1)Percent change includes reinvestment of $0.040 per share capital
   gains distributions.
(2)Percent change includes reinvestment of $0.624 per share ordinary
   income dividends and $0.040 per share capital gains distributions.
(3)Percent change includes reinvestment of $0.149 per share ordinary
   income dividends.
(4)Percent change includes reinvestment of $0.567 per share ordinary
   income dividends and $0.040 per share capital gains distributions.
(5)Percent change includes reinvestment of $0.136 per share ordinary
   income dividends.
</TABLE>

<PAGE>
PORTFOLIO ABBREVIATIONS

To simplify the listing of Merrill Lynch Pennsylvania
Municipal Bond Fund's portfolio holdings in the Schedule
of Investments, we have abbreviated the names of many
of the securities according to the list below and at right.

AMT               Alternative Minimum Tax (subject to)
COP               Certificates of Participation
GO                General Obligation Bonds
HFA               Housing Finance Authority
IDA               Industrial Development Authority
IDR               Industrial Development Revenue Bonds
LT                Limited Tax
M/F               Multi-Family
MVRICS            Municipal Variable Rate Inverse Class Securities
PCR               Pollution Control Revenue Bonds
RIB               Residual Interest Bonds
S/F               Single-Family
UT                Unlimited Tax
VRDN              Variable Rate Demand Notes



<TABLE>
SCHEDULE OF INVESTMENTS                                                                                    (in Thousands)
<CAPTION>
S&P     Moody's   Face                                                                                            Value
Ratings Ratings  Amount                               Issue                                                     (Note 1a)

Pennsylvania--93.4%
<S>      <S>    <C>       <S>                                                                                    <C>
AAA      Aaa    $   500   Allegheny County, Pennsylvania, Airport Revenue Bonds (Greater Pittsburgh
                          International Airport), AMT, Series C, 8.25% due 1/01/2016 (c)(k)                      $    558

NR       A        1,575   Allegheny County, Pennsylvania, Higher Education Building Authority Revenue
                          Bonds (Community College of Allegheny County), Series A, 5.80% due 6/01/2013              1,502

BBB      NR         500   Allegheny County, Pennsylvania, Hospital Development Authority, Health and
                          Education Revenue Bonds (Rehabilitation Institute of Pittsburgh), 7% due
                          6/01/2022                                                                                   502
<PAGE>
                          Allegheny County, Pennsylvania, Hospital Development Authority, Presbyterian
                          Health Center Revenue Bonds, VRDN (a)(c):
A1+      VMIG1      700     Series A, 2.85% due 3/01/2020                                                             700
A1+      VMIG1    1,400     Series C, 2.85% due 3/01/2020                                                           1,400
A1+      VMIG1      100     Series D, 2.85% due 3/01/2020                                                             100

AAA      Aaa        475   Allegheny County, Pennsylvania, Institutional District Bonds, UT, Series 18,
                          7.30% due 4/20/2009 (c)                                                                     515

NR       Aaa        575   Allegheny County, Pennsylvania, Residential Finance Authority, S/F Mortgage
                          Revenue Bonds, Series L, 7.50% due 6/01/2015 (e)                                            590

                          Allegheny County, Pennsylvania, Sanitation Authority, Sewer Revenue Bonds:
AAA      Aaa      5,265     Refunding, 5.85% due 12/01/2016 (d)(j)                                                  1,286
AAA      Aaa      3,000     Series B, 6% due 12/01/2011 (c)                                                         3,013
AAA      Aaa        750     Series C, 6.50% due 12/01/2001 (d)(f)                                                     815

AAA      Aaa      1,250   Beaver County, Pennsylvania, Hospital Authority Revenue Bonds (Medical
                          Center of Beaver, Pennsylvania, Inc.), Series A, 6.25% due 7/01/2022 (b)                  1,250

AAA      Aaa        500   Beaver County, Pennsylvania, IDA, PCR, Refunding (Ohio Edison Project),
                          Series A, 7.75% due 9/01/2024 (d)                                                           562

AAA      Aaa      2,000   Bristol Township, Pennsylvania, School District, GO, Series A, 6.625% due
                          2/15/2002 (c)(f)                                                                          2,203

AAA      Aaa      1,000   Bucks County, Pennsylvania, IDA, Revenue Bonds (Grand View Hospital Project),
                          7% due 7/01/2001 (b)(f)                                                                   1,124

NR       A1         750   Central Bucks County, Pennsylvania, School District, GO, 6.90% due 2/01/2008                798

AAA      Aaa        815   Danville, Pennsylvania, Area School District, GO, 6% due 5/01/2007 (c)                      819

NR       Baa        500   Dauphin County, Pennsylvania, IDA, Water Development Revenue Bonds (Dauphin
                          Consolidated Water Supply), AMT, Series A, 6.90% due 6/01/2024                              536

AAA      Aaa        575   Delaware County, Pennsylvania, College Authority Revenue Bonds (Haverford College),
                          7.375% due 11/15/2000 (c)(f)                                                                657
</TABLE>
<PAGE>
<TABLE>
SCHEDULE OF INVESTMENTS (continued)                                                                        (in Thousands)
<CAPTION>
S&P     Moody's   Face                                                                                            Value
Ratings Ratings  Amount                               Issue                                                     (Note 1a)

Pennsylvania (continued)
<S>      <S>    <C>       <S>                                                                                    <C>
A-       NR     $ 2,600   Delaware County, Pennsylvania, Hospital Authority Revenue Bonds (Riddle
                          Memorial Hospital), 6.50% due 1/01/2022                                                $  2,519

A+       Aa3      1,000   Delaware County, Pennsylvania, IDA, Revenue Refunding Bonds (Resources Recovery
                          Project), Series A, 8.10% due 12/01/2013                                                  1,064

NR       NR         500   Delaware County, Pennsylvania, University Authority Revenue Bonds (Villanova
                          University), 7.75% due 8/01/1998 (f)                                                        561

AAA      Aaa      2,450   Derry, Pennsylvania, Area School District, GO, 6.50% due 2/01/2001 (c)(f)                 2,634
                          Erie County, Pennsylvania, IDA, PCR, Refunding (International Paper Co.):
A-       A3       1,000     7.15% due 9/01/2013                                                                     1,046
A-       A3         425     Series A, 7.60% due 9/01/2010                                                             457

AAA      Aaa      1,155   Exeter Township, Pennsylvania, School District, GO, UT, 6.65% due 5/15/2010 (d)           1,212

A-       NR       4,990   Gettysburg, Pennsylvania, Municipal Authority, College Revenue Refunding Bonds
                          (Gettysburg College Project), 6.60% due 2/15/2012                                         5,082

AAA      Aaa        705   Gettysburg, Pennsylvania, Municipal Authority, Water Revenue Refunding Bonds,
                          6.25% due 10/01/2009 (c)(l)                                                                 715

AAA      Aaa      2,000   Lancaster County, Pennsylvania, Hospital Authority Revenue Refunding Bonds
                          (Health Center--Masonic Homes Project), 5.50% due 11/15/2014 (b)                          1,850

NR       Baa1     1,500   Latrobe, Pennsylvania, IDA, College Revenue Bonds (Saint Vincent College Project),
                          6.75% due 5/01/2024                                                                       1,492

BBB+     NR       2,000   Lebanon County, Pennsylvania, Good Samaritan Hospital Authority, Revenue
                          Refunding Bonds (Good Samaritan Hospital Project), 6% due 11/15/2018                      1,802

AAA      Aaa      1,250   Lehigh County, Pennsylvania, GO, UT, Series A, 6% due 10/15/1999 (b)(f)                   1,311

AAA      Aaa      1,000   Lewisburg, Pennsylvania, Area School District, GO, UT, 6.25% due 6/01/2018 (c)            1,006

                          Luzerne County, Pennsylvania, IDA, Exempt Facilities Revenue Bonds (Pennsylvania
                          Gas & Water Co. Project):
BBB-     Baa3     2,100     Refunding, Series A, 6.05% due 1/01/2019                                                1,951
BBB-     Baa3     1,500     Series B, AMT, 7.125% due 12/01/2022                                                    1,526
<PAGE>
NR       Baa1     2,000   McKeesport, Pennsylvania, Hospital Authority Revenue Bonds (McKeesport
                          Hospital Project), 6.50% due 7/01/2008                                                    2,019

                          Montgomery County, Pennsylvania, Higher Education and Health Authority, Hospital
                          Revenue Bonds:
AAA      Aaa      2,500     (Abington Hospital), MVRICS, Series A, 10.045% due 6/01/2011 (b)(m)                     2,703
BBB      NR         225     (Jeanes Health System Project), 8.625% due 7/01/2000 (f)                                  270
BBB      NR         575     (Jeanes Health System Project), 8.75% due 7/01/2000 (f)                                   692
BBB+     NR       1,250     (Pottstown Memorial Medical Center Project), 7.35% due 11/15/2005                       1,313

BBB+     NR         475   Moon Transportation Authority, Pennsylvania, Highway Improvement Revenue Bonds,
                          9.50% due 2/01/2016 (l)                                                                     527

BBB      NR       1,435   Montgomery County, Pennsylvania, Higher Educational and Health Authority
                          Revenue Bonds (Northwestern Corp.), 7% due 6/01/2012                                      1,454

A        A2       3,000   New Morgan, Pennsylvania, IDA, Solid Waste Disposal Revenue Bonds (New Morgan
                          Landfill Company Inc. Project), AMT, 6.50% due 4/01/2019                                  2,974

BBB-     NR       2,095   Northampton County, Pennsylvania, Higher Education Authority Revenue Bonds
                          (Moravian College), 8.20% due 6/01/2011                                                   2,376
</TABLE>

<TABLE>
SCHEDULE OF INVESTMENTS (continued)                                                                        (in Thousands)
<CAPTION>
S&P     Moody's   Face                                                                                            Value
Ratings Ratings  Amount                               Issue                                                     (Note 1a)

Pennsylvania (continued)
<S>      <S>    <C>       <S>                                                                                    <C>
BBB      NR     $ 1,500   Northeastern Pennsylvania Hospital and Educational Authority, University
                          Revenue Refunding Bonds (Wilkes University), 5.625% due 10/01/2018                     $  1,336

AAA      Aaa      2,000   Pennsylvania, HFA, Refunding, Rental Housing Bonds, 6.50% due 7/01/2023 (h)               2,004

AA       Aa       2,000   Pennsylvania, HFA, RIB, AMT, 8.73% due 4/01/2025 (m)                                      1,800

AA       Aa       1,000   Pennsylvania, HFA, RIB, Refunding, Series 1991-31C, AMT, 10.674% due
                          10/01/2023 (m)                                                                            1,039

AA       NR         500   Pennsylvania Infrastructure Investment Authority Revenue Bonds, Pennvest Sub-
                          Series B, 6.80% due 9/01/2010                                                               529

                          Pennsylvania Intergovernmental Cooperative Authority, City of Philadelphia
                          Funding Program, Special Tax Revenue Bonds:
NR       Baa      2,000     6.80% due 6/15/2002 (f)                                                                 2,203
AAA      Aaa      2,570     5.625% due 6/15/2023 (c)                                                                2,369

A        NR       2,000   Pennsylvania State Finance Authority, Revenue Refunding Bonds (Municipal
                          Capital Improvements Program), 6.60% due 11/01/2009                                       2,067
<PAGE>
AA-      NR       1,300   Pennsylvania State, GO, Series A, 7% due 5/01/2000 (f)                                    1,441
                          Pennsylvania State, HFA, S/F Mortgage Revenue Bonds, AMT:
AA       Aa       1,730     Series 27, 8.15% due 10/01/2021                                                         1,850
AA       Aa       1,145     Series 28, 7.65% due 10/01/2023                                                         1,183

A-1+     VMIG1    3,300   Pennsylvania State Higher Education Assistance Agency, Student Loan Revenue
                          Bonds, Series B, AMT, VRDN, 2.35% due 7/01/2018 (a)                                       3,300

                          Pennsylvania State Higher Educational Facilities Authority, College and
                          University Revenue Bonds:
A+       NR       1,000     (Carnegie Mellon University), 9% due 11/01/2009                                         1,082
NR       Baa      2,295     (Delaware Valley College of Science & Agriculture), 7% due 4/01/2022                    2,295
AAA      Aaa        270     (Drexel University), 1st Series, 7.70% due 5/01/2012 (c)                                  287
NR       NR       1,030     (Pennsylvania College Podiatric Medicine), 8.50% due 10/01/2014                         1,093
BBB+     NR       1,250     Refunding (Allegheny College Project), Series B, 6% due 11/01/2022                      1,153

                          Pennsylvania State Higher Educational Facilities Authority, Revenue Refunding
                          Bonds:
BBB+     NR       2,300     (Drexel University), 6.375% due 5/01/2017                                               2,258
A+       Aa       2,000     (Thomas Jefferson University), Series A, 6.625% due 8/15/2009                           2,092

                          Pennsylvania State, IDA, Economic Development Revenue Bonds:
AAA      Aaa      3,440     6% due 1/01/2012 (b)                                                                    3,440
A-       A        1,225     Series A, 7% due 7/01/2001 (f)                                                          1,373

                          Pennsylvania State Turnpike Commission, Turnpike Revenue Bonds (f):
AAA      Aaa        250     Series H, 7.40% due 12/01/2000 (d)                                                        285
AAA      Aaa      1,500     Series J, 7.20% due 12/01/2001 (d)                                                      1,709
AAA      Aaa        700     Series K, Custodian Receipts/Certificates, 7.50% due 12/01/1999                           796

                          Philadelphia, Pennsylvania, Authority for IDR:
A-1      VMIG1      200     (Commercial-Development-Philadelphia Airport Hotel), AMT, VRDN,
                            3.05% due 12/01/2017 (a)                                                                  200
AAA      Aaa        375     (Conversion Project-PGH Development Corp.), 7% due 7/01/1999 (b)(f)                       414
A+       NR       1,895     (National Board of Medical Examiners Project), 6.75% due 5/01/2012                      2,030
</TABLE>

<TABLE>
SCHEDULE OF INVESTMENTS (continued)                                                                        (in Thousands)
<CAPTION>
S&P     Moody's   Face                                                                                            Value
Ratings Ratings  Amount                               Issue                                                     (Note 1a)

Pennsylvania (continued)
<S>      <S>    <C>       <S>                                                                                    <C>
                          Philadelphia, Pennsylvania, Gas Works Revenue Bonds:
AAA      Aaa    $   370     11th Series A, 7.875% due 7/01/1997 (f)                                              $    409
AAA      Aaa        750     13th Series, 7.70% due 6/15/2001 (f)                                                      872
AAA      Aaa        500     12th Series B, 7% due 5/15/2020 (c)(n)                                                    578
BBB      Baa1     2,925     Refunding, 14th Series A, 6.375% due 7/01/2014                                          2,925
BBB      Baa1     5,250     Refunding, 14th Series A, 6.375% due 7/01/2026                                          5,134
<PAGE>
                          Philadelphia, Pennsylvania, Hospitals and Higher Education Facilities Authority
                          Revenue Bonds:
NR       Aaa      1,400     (Children's Hospital Philadelphia Project), Series A, 6.50% due 2/15/2002 (f)           1,533
A-       NR       1,015     (Children's Seashore House), Series A, 7% due 8/15/2017                                 1,050
A-       NR       1,355     (Children's Seashore House), Series B, 7% due 8/15/2022                                 1,394
BBB      NR       3,100     (Northern Corp.), 7.125% due 6/01/2018                                                  3,164
AAA      Aaa        500     Refunding (Magee Rehabilitation Hospital), 7% due 12/01/2005 (b)                          546
AAA      Aaa      1,000     Refunding (Magee Rehabilitation Hospital), 7% due 12/01/2010 (b)                        1,091
A        A          420     Refunding (Pennsylvania Hospital), 7.25% due 7/01/2014                                    441
BBB+     NR       1,000     Refunding (Philadelphia MR Project), 6.20% due 8/01/2011                                  960
A-       NR       3,000     Refunding (Presbyterian Medical Center), 6.65% due 12/01/2019                           2,978
BBB+     Baa1     2,500     Refunding (Temple University Hospital), Series A, 6.625% due 11/15/2023                 2,387

                          Philadelphia, Pennsylvania, Municipal Authority, Revenue Refunding Bonds (d):
AAA      Aaa         40     7.80% due 4/01/1998 (f)                                                                    45
AAA      Aaa        360     7.80% due 4/01/2000 (f)                                                                   409
AAA      Aaa      1,000     (Lease), Series C, 5.25% due 4/01/2018                                                    877

NR       Aaa        990   Philadelphia, Pennsylvania, Redevelopment Authority, M/F Housing Revenue
                          Refunding Bonds (Washington Square West), Series C, 6.95% due 11/15/2024 (h)(i)           1,020

                          Philadelphia, Pennsylvania, Water and Sewer Revenue Bonds:
AAA      Baa        745     11th Series, Sub-Series B, 9.10% due 10/01/1995 (f)                                       801
BBB      Baa      1,000     16th Series, 7.50% due 8/01/2010                                                        1,086

BBB      Baa      2,000   Philadelphia, Pennsylvania, Water and Wastewater Revenue Refunding Bonds,
                          5.75% due 6/15/2013                                                                       1,840

AAA      Aaa      2,000   Pittsburgh, Pennsylvania, Revenue Bonds, Series B, 6.25% due 9/01/2016 (c)                2,022

AAA      Aaa      1,000   Reading, Pennsylvania, Refunding Bonds, GO, UT, 6.50% due 11/15/2002 (b)(f)               1,089

                          Sayre, Pennsylvania, Health Care Facilities Authority Revenue Bonds, VHA
                          (Pennsylvania Capital Financing Project), VRDN (a)(b):
A-1      Aaa      2,200     Series B, 2.85% due 12/01/2020                                                          2,200
A-2      Aaa      1,000     Series I, 2.85% due 12/01/2020                                                          1,000

A-1      NR         500   Schuylkill County, Pennsylvania, IDA, Resource Recovery Revenue Bonds (North-
                          eastern Power Company), VRDN, 2.75% due 12/01/2011 (a)                                      500
</TABLE>
<PAGE>
<TABLE>
SCHEDULE OF INVESTMENTS (concluded)                                                                        (in Thousands)
<CAPTION>
S&P     Moody's   Face                                                                                            Value
Ratings Ratings  Amount                               Issue                                                     (Note 1a)

Pennsylvania (concluded)
<S>      <S>    <C>       <S>                                                                                    <C>
                          Scranton-Lackawanna, Pennsylvania, Health and Welfare Authority Revenue Bonds
                          (University of Scranton Project):
A-       NR     $ 1,750     Refunding, Series A, 6.50% due 3/01/2013                                             $  1,771
NR       NR         460     Series C, 7.50% due 6/15/2000 (f)                                                         525

AAA      Aaa      1,000   York County, Pennsylvania, Hospital Authority Revenue Bonds (York Hospital),
                          7% due 7/01/2001 (b)(f)                                                                   1,116

A1+      P1       3,200   York County, Pennsylvania, IDA, PCR, Refunding (Philadelphia Electric Company),
                          VRDN, Series A, 2.80% due 8/01/2016 (a)                                                   3,200

AAA      Aaa      2,000   York County, Pennsylvania, GO, LT, South Western School District, 6.40% due
                          6/15/2012 (d)                                                                             2,080

Puerto Rico--5.8%

                          Puerto Rico Commonwealth, Aqueduct and Sewer Authority Revenue Bonds, Series A:
BB       Baa      2,150     7.875% due 7/01/2017                                                                    2,337
BB       Baa        310     7% due 7/01/2019                                                                          323

A        Baa1       800   Puerto Rico Commonwealth, Highway Authority, Highway Revenue Refunding Bonds,
                          Series R, 6.75% due 7/01/2005                                                               870

AAA      NR         740   Puerto Rico Commonwealth, Public Improvement GO, 7.70% due 7/01/2000 (f)                    857

                          Puerto Rico Electric Power Authority, Power Revenue Refunding Bonds:
AAA      Baa1       100     Refunding, Series M, 8% due 7/01/1998 (f)                                                 113
A-       Baa1       335     Series O, 7.125% due 7/01/1999 (f)                                                        373
A-       Baa1       190     Series O, 7.125% due 7/01/2014                                                            203
A-       Baa1     2,000     Series R, 6.25% due 7/01/2017                                                           2,010

A        Baa1     2,365   Puerto Rico Public Buildings Authority, Guaranteed Public Education and
                          Health Facilities, Refunding Bonds, Series M, 5.50% due 7/01/2021                         2,124
<PAGE>
Total Investments (Cost--$153,720)--99.2%                                                                         157,367
Other Assets Less Liabilities--0.8%                                                                                 1,290
                                                                                                                 --------
Net Assets--100.0%                                                                                               $158,657
                                                                                                                 ========

<FN>
(a)The interest rate is subject to change periodically based upon
   prevailing market rates. The interest rate shown is the rate in
   effect at July 31, 1994.
(b)AMBAC Insured.
(c)MBIA Insured.
(d)FGIC Insured.
(e)GNMA Collateralized.
(f)Prerefunded.
(g)FSA Insured.
(h)FNMA Collateralized.
(i)FHA Insured.
(j)Represents the yield to maturity on this zero coupon issue.
(k)Partial Prerefunded.
(l)Bank Qualified.
(m) The interest rate is subject to change periodically and
   inversely based upon prevailing market rates. The interest rate
   shown is the rate in effect at July 31, 1994.
(n)Escrowed to Maturity.
   Ratings of issues shown have not been audited by Deloitte & Touche
   LLP.


See Notes to Financial Statements.
</TABLE>



FINANCIAL INFORMATION

<TABLE>
Statement of Assets and Liabilities as of July 31, 1994
<CAPTION>
<S>             <S>                                                                          <C>             <C>
Assets:         Investments, at value (identified cost--$153,720,472) (Note 1a)                              $157,366,771
                Cash                                                                                               60,215
                Receivables:
                  Interest                                                                   $  2,151,508
                  Beneficial interest sold                                                        276,985       2,428,493
                                                                                             ------------
                Deferred organization expenses (Note 1e)                                                           17,452
                Prepaid registration fees and other assets (Note 1e)                                               29,305
                                                                                                             ------------
                Total assets                                                                                  159,902,236
                                                                                                             ------------
<PAGE>
Liabilities:    Payables:
                  Beneficial interest redeemed                                                    907,979
                  Dividends to shareholders (Note 1f)                                             132,136
                  Investment adviser (Note 2)                                                      73,842
                  Distributor (Note 2)                                                             55,154       1,169,111
                                                                                             ------------
                Accrued expenses and other liabilities                                                             76,132
                                                                                                             ------------
                Total liabilities                                                                               1,245,243
                                                                                                             ------------

Net Assets:     Net assets                                                                                   $158,656,993
                                                                                                             ============

Net Assets      Class A--Shares of beneficial interest, $.10 par value, unlimited
Consist of:     number of shares authorized                                                                  $    256,812
                Class B--Shares of beneficial interest, $.10 par value, unlimited
                number of shares authorized                                                                     1,186,088
                Paid-in capital in excess of par                                                              153,830,099
                Accumulated distribution in excess of realized capital gains--net                                (262,305)
                Unrealized appreciation on investments--net                                                     3,646,299
                                                                                                             ------------
                Net assets                                                                                   $158,656,993
                                                                                                             ============

Net Asset       Class A--Based on net assets of $28,239,285 and 2,568,115 shares of
Value:          beneficial interest outstanding                                                              $      11.00
                                                                                                             ============
                Class B--Based on net assets of $130,417,708 and 11,860,884 shares of
                beneficial interest outstanding                                                              $      11.00
                                                                                                             ============

                See Notes to Financial Statements.
</TABLE>


FINANCIAL INFORMATION (continued)

<TABLE>
Statement of Operations
<CAPTION>
                                                                                                       For the Year Ended
                                                                                                            July 31, 1994
<S>             <S>                                                                                          <C>
Investment      Interest and amortization of premium and discount earned                                     $  9,378,981
Income                                                                                                       
(Note 1d):
<PAGE>
Expenses:       Investment advisory fees (Note 2)                                                                 852,481
                Distribution fees--Class B (Note 2)                                                               629,787
                Transfer agent fees--Class B (Note 2)                                                              58,820
                Accounting services (Note 2)                                                                       58,164
                Professional fees                                                                                  51,515
                Printing and shareholder reports                                                                   50,057
                Registration fees (Note 1e)                                                                        21,316
                Custodian fees                                                                                     19,820
                Amortization of organization expenses (Note 1e)                                                    16,208
                Pricing fees                                                                                       14,615
                Transfer agent fees--Class A (Note 2)                                                              11,686
                Trustees' fees and expenses                                                                         6,324
                Other                                                                                               2,739
                                                                                                             ------------
                Total expenses                                                                                  1,793,532
                                                                                                             ------------
                Investment income--net                                                                          7,585,449
                                                                                                             ------------

Realized &      Realized gain on investments--net                                                                  96,923
Unrealized      Change in unrealized appreciation on investments--net                                          (5,481,887)
Gain on                                                                                                      ------------
Investments     Net Increase in Net Assets Resulting from Operations                                         $  2,200,485
- --Net (Notes                                                                                                 ============
1d & 3):

                See Notes to Financial Statements.
</TABLE>

FINANCIAL INFORMATION (continued)

<TABLE>
Statements of Changes in Net Assets
<CAPTION>
                                                                                              For the Year Ended July 31,
Increase (Decrease) in Net Assets:                                                               1994             1993
<S>             <S>                                                                          <C>             <C>
Operations:     Investment income--net                                                       $  7,585,449    $  5,696,106
                Realized gain on investments--net                                                  96,923         495,162
                Change in unrealized appreciation on investments--net                          (5,481,887)      3,612,233
                                                                                             ------------    ------------
                Net increase in net assets resulting from operations                            2,200,485       9,803,501
                                                                                             ------------    ------------
<PAGE>
Dividends &     Investment income--net:
Distribu-         Class A                                                                      (1,539,524)     (1,219,822)
tions to          Class B                                                                      (6,045,925)     (4,476,284)
Shareholders    Realized gain on investments--net:
(Note 1f):        Class A                                                                        (111,974)        (10,105)
                  Class B                                                                        (480,111)        (44,305)
                In excess of realized gain on investments--net:
                  Class A                                                                         (49,607)             --
                  Class B                                                                        (212,698)             --
                                                                                             ------------    ------------
                Net decrease in net assets resulting from dividends and
                distributions to shareholders                                                  (8,439,839)     (5,750,516)
                                                                                             ------------    ------------

Beneficial      Net increase in net assets derived from beneficial interest
Interest        transactions                                                                   27,793,932      50,306,502
Transactions                                                                                 ------------    ------------
(Note 4):

Net Assets:     Net increase in net assets                                                     21,554,578      54,359,487
                Beginning of year                                                             137,102,415      82,742,928
                                                                                             ------------    ------------
                End of year                                                                  $158,656,993    $137,102,415
                                                                                             ============    ============

                See Notes to Financial Statements.
</TABLE>

FINANCIAL INFORMATION (continued)
<PAGE>
<TABLE>
Financial Highlights
<CAPTION>
                                                                                       Class A
                                                                                                               For the
                                                                                                                Period
The following per share data and ratios have been derived                                                      Aug. 31,
from information provided in the financial statements.                                                        1990++ to
                                                                           For the Year Ended July 31,         July 31,
Increase (Decrease) in Net Asset Value:                                  1994          1993         1992         1991
<S>             <S>                                                    <C>          <C>          <C>           <C>
Per Share       Net asset value beginning of period                    $   11.39    $   11.04    $   10.27     $   10.00
Operating                                                              ---------    ---------    ---------     ---------
Performance:      Investment income--net                                     .60          .63          .67           .61
                  Realized and unrealized gain (loss)
                  on investments--net                                       (.33)         .36          .77           .27
                                                                       ---------    ---------    ---------     ---------
                Total from investment operations                             .27          .99         1.44           .88
                                                                       ---------    ---------    ---------     ---------
                Less dividends and distributions:
                  Investment income--net                                    (.60)        (.63)        (.67)         (.61)
                  Realized gain on investments--net                         (.04)        (.01)          --            --
                In excess of realized gain on investments--net              (.02)          --           --            --
                                                                       ---------    ---------    ---------     ---------
                Total dividends and distributions                           (.66)        (.64)        (.67)         (.61)
                                                                       ---------    ---------    ---------     ---------
                Net asset value, end of period                         $   11.00    $   11.39    $   11.04     $   10.27
                                                                       =========    =========    =========     =========

Total           Based on net asset value per share                         2.37%        9.30%       14.53%         9.30%+++
Investment                                                             =========    =========    =========     =========
Return:**

Ratios to       Expenses, net of reimbursement                              .75%         .69%         .55%         .39%*
Average                                                                =========    =========    =========     =========
Net Assets:     Expenses                                                    .75%         .81%         .97%        1.57%*
                                                                       =========    =========    =========     =========
                Investment income--net                                     5.30%        5.70%        6.33%        6.71%*
                                                                       =========    =========    =========     =========

Supplemental    Net assets, end of period (in thousands)               $  28,239    $  27,639    $  17,144     $   9,402
Data:                                                                  =========    =========    =========     =========
                Portfolio turnover                                        37.73%        9.69%        4.14%            --
                                                                       =========    =========    =========     =========

             <FN>
              ++Commencement of Operations.
             +++Aggregate total investment return.
               *Annualized.
              **Total investment returns exclude the effects of sales loads.

                See Notes to Financial Statements.
</TABLE>
<PAGE>

FINANCIAL INFORMATION (concluded)

<TABLE>
Financial Highlights (concluded)
<CAPTION>
                                                                                           Class B
                                                                                                                For the
                                                                                                                Period
The following per share data and ratios have been derived                                                       Aug. 31,
from information provided in the financial statements.                                                         1990++ to
                                                                              For the Year Ended July 31,       July 31,
Increase (Decrease) in Net Asset Value:                                   1994         1993         1992          1991
<S>             <S>                                                    <C>          <C>          <C>           <C>   
Per Share       Net asset value beginning of period                    $   11.39    $   11.04    $   10.27     $   10.00
Operating                                                              ---------    ---------    ---------     ---------
Performance:      Investment income--net                                     .54          .58          .62           .57
                  Realized and unrealized gain (loss)
                  on investments--net                                       (.33)         .36          .77           .27
                                                                       ---------    ---------    ---------     ---------
                Total from investment operations                             .21          .94         1.39           .84
                                                                       ---------    ---------    ---------     ---------
                Less dividends and distributions:
                  Investment income--net                                    (.54)        (.58)        (.62)         (.57)
                  Realized gain on investments--net                         (.04)        (.01)          --            --
                In excess of realized capital gain on 
                investments--net                                            (.02)          --           --            --
                                                                       ---------    ---------    ---------     ---------
                Total dividends and distributions                           (.60)        (.59)        (.62)         (.57)
                                                                       ---------    ---------    ---------     ---------
                Net asset value, end of period                         $   11.00    $   11.39    $   11.04     $   10.27
                                                                       =========    =========    =========     =========

Total           Based on net asset value per share                         1.86%        8.75%       13.94%         8.81%+++
Investment                                                             =========    =========    =========     =========
Return:**

Ratios to       Expenses, excluding distribution fees
Average         and net of reimbursement                                    .75%         .69%         .56%         .40%*
Net Assets:                                                            =========    =========    =========     =========
                Expenses, net of reimbursement                             1.25%        1.19%        1.06%         .90%*
                                                                       =========    =========    =========     =========
                Expenses                                                   1.25%        1.32%        1.48%        2.07%*
                                                                       =========    =========    =========     =========
                Investment income--net                                     4.80%        5.19%        5.81%        6.21%*
                                                                       =========    =========    =========     =========
<PAGE>
Supplemental    Net assets, end of period (in thousands)               $ 130,418    $ 109,463    $  65,599     $  30,435
Data:                                                                  =========    =========    =========     =========
                Portfolio turnover                                        37.73%        9.69%        4.14%            --
                                                                       =========    =========    =========     =========

             <FN>
              ++Commencement of Operations.
             +++Aggregate total investment return.
               *Annualized.
              **Total investment returns exclude the effects of sales loads.

                See Notes to Financial Statements.
</TABLE>


NOTES TO FINANCIAL STATEMENTS



1. Significant Accounting Policies:
Merrill Lynch Pennsylvania Municipal Bond Fund (the "Fund") is part
of Merrill Lynch Multi-State Municipal Series Trust (the "Trust").
The Fund is registered under the Investment Company Act of 1940 as a
non-diversified, open-end management investment company. The Fund
offers both Class A and Class B Shares. Class A Shares are sold with
a front-end sales charge. Class B Shares may be subject to a
contingent deferred sales charge. Both classes of shares have
identical voting, dividend, liquidation and other rights and the
same terms and conditions, except that Class B Shares bear certain
expenses related to the distribution of such shares and have
exclusive voting rights with respect to matters relating to such
distribution expenditures. The following is a summary of significant
accounting policies followed by the Fund.

(a) Valuation of investments--Municipal bonds and other portfolio
securities in which the Fund invests are traded primarily in the
over-the-counter municipal bond and money markets and are valued at
the last available bid price in the over-the-counter market or on
the basis of yield equivalents as obtained from one or more dealers
that make markets in the securities. Financial futures contracts and
options thereon, which are traded on exchanges, are valued at their
settlement prices as of the close of such exchanges. Short-term
investments with a remaining maturity of sixty days or less are
valued on an amortized cost basis, which approximates market value.
Options, which are traded on exchanges, are valued at their last
sale price as of the close of such exchanges or, lacking any sales,
at the last available bid price. Securities and assets for which
market quotations are not readily available are valued at fair value
as determined in good faith by or under the direction of the Board
of Trustees of the Trust, including valuations furnished by a
pricing service retained by the Trust, which may utilize a matrix
system for valuations. The procedures of the pricing service and its
valuations are reviewed by the officers of the Trust under the
general supervision of the Trustees.
<PAGE>
(b) Financial futures contracts--The Fund may purchase or sell
interest rate futures contracts and options on such futures
contracts for the purpose of hedging the market risk on existing
securities or the intended purchase of securities. Futures contracts
are contracts for delayed delivery of securities at a specific
future date and at a specific price or yield. Upon entering into a
contract, the Fund deposits and maintains as collateral such initial
margin as required by the exchange on which the transaction is
effected. Pursuant to the contract, the Fund agrees to receive from
or pay to the broker an amount of cash equal to the daily
fluctuation in value of the contract. Such receipts or payments are
known as variation margin and are recorded by the Fund as unrealized
gains or losses. When the contract is closed, the Fund records a
realized gain or loss equal to the difference between the value of
the contract at the time it was opened and the value at the time it
was closed.

(c) Income taxes--It is the Fund's policy to comply with the
requirements of the Internal Revenue Code applicable to regulated
investment companies and to distribute substantially all of its
taxable income to its shareholders. Therefore, no Federal income tax
provision is required.

(d) Security transactions and investment income--Security
transactions are recorded on the dates the transactions are entered
into (the trade dates). Interest income is recognized on the accrual
basis. Original issue discounts and market premiums are amortized
into interest income. Realized gains and losses on security
transactions are determined on the identified cost basis.

(e) Deferred organization expenses and prepaid registration fees--
Deferred organization expenses are charged to expense on a straight-
line basis over a five-year period. Prepaid registration fees are
charged to expense as the related shares are issued.

(f) Dividends and distributions--Dividends from net investment
income are declared daily and paid monthly. Distributions of capital
gains are recorded on the ex-dividend dates. Distributions in excess
of realized capital gains are due primarily to differing tax
treatments for futures transactions and post October losses.


NOTES TO FINANCIAL STATEMENTS (concluded)

<PAGE>
2. Investment Advisory Agreement and Transactions with Affiliates:
The Fund has entered into an Investment Advisory Agreement with Fund
Asset Management, L.P. ("FAM"). Effective January 1, 1994, the
investment advisory business of FAM was reorganized from a
corporation to a limited partnership. Both prior to and after the
reorganization, ultimate control of FAM was vested with Merrill
Lynch & Co., Inc. ("ML & Co."). The general partner of FAM is
Princeton Services, Inc. ("PSI"), an indirect wholly-owned
subsidiary of ML & Co. The limited partners are ML & Co. and Fund
Asset Management, Inc. ("FAMI"), which is also an indirect wholly-
owned subsidiary of ML & Co. The Fund has also entered into
Distribution Agreements and a Distribution Plan with Merrill Lynch
Funds Distributor, Inc. ("MLFD" or "Distributor"), a wholly-owned
subsidiary of Merrill Lynch Investment Management, Inc. ("MLIM"),
which is also a wholly-owned subsidiary of ML & Co.

FAM is responsible for the management of the Fund's portfolio and
provides the necessary personnel, facilities, equipment and certain
other services necessary to the operations of the Fund.

For such services, the Fund pays a monthly fee based upon the
average daily value of the Fund's net assets at the following annual
rates: 0.55% of the Fund's average daily net assets not exceeding
$500 million; 0.525% of average daily net assets in excess of $500
million but not exceeding $1 billion; and 0.50% of average daily net
assets in excess of $1 billion. The Investment Advisory Agreement
obligates FAM to reimburse the Fund to the extent the Fund's
expenses (excluding interest, taxes, distribution fees, brokerage
fees and commissions, and extraordinary items) exceed 2.5% of the
Fund's first $30 million of average daily net assets, 2.0% of the
next $70 million of average daily net assets, and 1.5% of the
average daily net assets in excess thereof. FAM's obligation to
reimburse the Fund is limited to the amount of the management fee.
No fee payment will be made to the Investment Adviser during any
fiscal year which will cause such expenses to exceed expense
limitations at the time of payment.

Pursuant to a distribution plan (the "Distribution Plan") adopted by
the Fund in accordance with Rule 12b-1 under the Investment Company
Act of 1940, the Fund pays the Distributor ongoing account
maintenance and distribution fees which are accrued daily and paid
monthly at the annual rate of 0.25% and 0.25%, respectively, of the
average daily net assets of the Class B Shares of the Fund. Pursuant
to a sub-agreement with the Distributor, Merrill Lynch, Pierce,
Fenner & Smith Inc. ("MLPF&S") also provides account maintenance and
distribution services to the Fund. As authorized by the Plan, the
Distributor has entered into an agreement with MLPF&S, an affiliate
of FAM, which provides for the compensation of MLPF&S for providing
distribution-related services to the Fund.
<PAGE>
For the year ended July 31, 1994, MLFD earned underwriting discounts
of $8,083, and MLPF&S earned dealer concessions of $85,614 on sales
of the Fund's Class A Shares.

MLPF&S also received contingent deferred sales charges of $204,747,
relating to Class B Share transactions during the period.

Financial Data Services, Inc. ("FDS"), a wholly-owned subsidiary of
ML & Co., is the Fund's transfer agent.

Accounting services are provided to the Fund by FAM at cost.

Certain officers and/or trustees of the Fund are officers and/or
directors of FAM, FAMI, PSI, MLIM, MLFD, FDS, MLPF&S, and/or ML &
Co.

3. Investments:
Purchases and sales of investments, excluding short-term securities,
for the year ended July 31, 1994 were $70,956,944 and $54,703,999,
respectively.

Net realized and unrealized gains (losses) as of July 31, 1994 were
as follows:

                                       Realized          Unrealized
Total                               Gains (Losses)         Gains

Long-term investments                $(1,077,165)       $ 3,646,299
Financial futures contracts            1,174,088                 --
                                     -----------        -----------
Total                                $    96,923        $ 3,646,299
                                     ===========        ===========

As of July 31, 1994, net unrealized appreciation for Federal income
tax purposes aggregated at $3,646,299, of which $5,827,047 related
to appreciated securities and $2,180,748 related to depreciated
securities. The aggregate cost of investments at July 31, 1994 for
Federal income tax purposes was $153,720,472.

4. Beneficial Interest Transactions:
Net increase in net assets derived from beneficial interest
transactions was $27,793,932 and $50,306,502 for the years ended
July 31, 1994 and July 31, 1993, respectively.

Transactions in shares of beneficial interest for Class A and Class
B Shares were as follows:
<PAGE>

Class A Shares for the                                     Dollar
Year Ended July 31, 1994                Shares             Amount

Shares sold                              550,023       $  6,297,702
Shares issued to shareholders
in reinvestment of dividends
and distributions                         80,433            915,022
                                     -----------        -----------
Total issued                             630,456          7,212,724
Shares redeemed                         (489,751)        (5,530,577)
                                     -----------        -----------
Net increase                             140,705        $ 1,682,147
                                     ===========        ===========


Class A Shares for the                                     Dollar
Year Ended July 31, 1993                Shares             Amount

Shares sold                              979,613        $10,925,850
Shares issued to shareholders
in reinvestment of dividends
and distributions                         55,368            613,668
                                     -----------        -----------
Total issued                           1,034,981         11,539,518
Shares redeemed                         (161,016)        (1,774,961)
                                     -----------        -----------
Net increase                             873,965        $ 9,764,557
                                     ===========        ===========


Class B Shares for the                                     Dollar
Year Ended July 31, 1994                Shares             Amount

Shares sold                            3,466,071        $39,679,393
Shares issued to shareholders
in reinvestment of dividends
and distributions                        296,534          3,370,692
                                     -----------        -----------
Total issued                           3,762,605         43,050,085
Shares redeemed                       (1,515,856)       (16,938,300)
                                     -----------        -----------
Net increase                           2,246,749        $26,111,785
                                     ===========        ===========

<PAGE>
Class B Shares for the                                     Dollar
Year Ended July 31, 1993                Shares             Amount

Shares sold                            4,193,436        $46,355,142
Shares issued to shareholders
in reinvestment of dividends
and distributions                        209,463          2,317,534
                                     -----------        -----------
Total issued                           4,402,899         48,672,676
Shares redeemed                         (732,907)        (8,130,731)
                                     -----------        -----------
Net increase                           3,669,992        $40,541,945
                                     ===========        ===========


<AUDIT-REPORT>
INDEPENDENT AUDITORS' REPORT

The Board of Trustees and Shareholders,
Merrill Lynch Pennsylvania Municipal Bond Fund of Merrill Lynch
Multi-State Municipal Series Trust:

We have audited the accompanying statement of assets and
liabilities, including the schedule of investments, of Merrill Lynch
Pennsylvania Municipal Bond Fund of Merrill Lynch Multi-State
Municipal Series Trust as of July 31, 1994, the related statements
of operations for the year then ended and changes in net assets for
each of the years in the two-year period then ended, and the
financial highlights for the three-year period then ended and for the
period August 31, 1990 (commencement of operations) to July 31,
1991. These financial statements and the financial highlights are the
responsibility of the Fund's management. Our responsibility is to
express an opinion on these financial statements and the financial
highlights based on our audits.

We conducted our audits in accordance with generally accepted
auditing standards. Those standards require that we plan and perform
the audit to obtain reasonable assurance about whether the financial
statements and the financial highlights are free of material
misstatement. An audit includes examining, on a test basis, evidence
supporting the amounts and disclosures in the financial statements.
Our procedures included confirmation of securities owned at July 31,
1994 by correspondence with the custodian. An audit also includes
assessing the accounting principles used and significant estimates
made by management, as well as evaluating the overall financial
statement presentation. We believe that our audits provide a
reasonable basis for our opinion.

In our opinion, such financial statements and financial highlights
present fairly, in all material respects, the financial position of
Merrill Lynch Pennsylvania Municipal Bond Fund of Merrill Lynch
Multi-State Municipal Series Trust as of July 31, 1994, the results
of its operations, the changes in its net assets, and the financial
highlights for the respective stated periods in conformity with
generally accepted accounting principles.

Deloitte & Touche LLP
Princeton, New Jersey
August 29, 1994
</AUDIT-REPORT>
<PAGE>

IMPORTANT TAX INFORMATION

All of the net investment income distributions paid monthly by
Merrill Lynch Pennsylvania Municipal Bond Fund during its taxable
year ended July 31, 1994 qualify as tax-exempt interest dividends
for Federal income tax purposes.

Additionally, the Fund distributed short-term capital gains of
$.022840 per share and long-term capital gains of $.040293 per share
to shareholders of record on December 22, 1993.

Please retain this information for your records.



OFFICERS AND TRUSTEES

Arthur Zeikel, President and Trustee
Kenneth S. Axelson, Trustee
Herbert I. London, Trustee
Robert R. Martin, Trustee
Joseph L. May, Trustee
Andre F. Perold, Trustee
Terry K. Glenn, Executive Vice President
Donald C. Burke, Vice President
Vincent R. Giordano, Vice President
Kenneth A. Jacob, Vice President
Gerald M. Richard, Treasurer
Jerry Weiss, Secretary

Custodian
National Westminster Bank NJ
10 Exchange Place
Jersey City, New Jersey 07302

Transfer Agent
Financial Data Services, Inc.
4800 Deer Lake Drive East
Jacksonville, Florida 32246-6484
(800) 637-3863
<PAGE>
APPENDIX: GRAPHIC AND IMAGE MATERIAL.

Item 1:

Total Return Based on a $10,000 Investment--Class A Shares*

A line graph depicting the growth of an investment in the Fund's Class A 
Shares compared to growth of an investment in the Lehman Brothers Municipal 
Bond Index.  Beginning and ending values are:
<PAGE>
				       	    8/31/90**	       	 7/94

ML Pennsylvania Municipal 
Bond Fund++                                  $ 9,600    	$13,446

Lehman Brothers
Municipal Bond Index++++		     $10,000		$13,915


[FN]
   *Assuming maximum sales charge, transaction costs and other operating 
    expenses including advisory fees.
  **Commencement of Operations.
  ++ML Pennsylvania Municipal Bond Fund invests primarily in long-term 
    investment-grade obligations issued by or on behalf of the Commonwealth 
    of Pennsylvania, its political subdivisions, agencies and instrumentalities
    and obligations of other qualifying issuers.
++++This unmanaged Index consists of long-term revenue bonds, prerefunded 
    bonds, general obligation bonds and insured bonds.

<PAGE>
Item 2:

Total Return Based on a $10,000 Investment--Class B Shares*

A line graph depicting the growth of an investment in the Fund's Class B Shares
compared to growth of an investment in the Lehman Brothers Municipal Bond 
Index. Beginning and ending values are:

					    8/31/90**	  	 7/94

ML Pennsylvania Municipal 
Bond Fund++	                             $10,000		$13,633

Lehman Brothers
Municipal Bond Index++++		     $10,000		$13,915

[FN]
   *Assuming maximum sales charge, transaction costs and other operating  
    expenses including advisory fees.
  **Commencement of Operations.
  ++ML Pennsylvania Municipal Bond Fund invests primarily in long-term invest-
    ment-grade obligations issued by or on behalf of the Commonwealth of 
    Pennsylvania, its political subdivisions, agencies and instrumentalities 
    and obligations of other qualifying issuers.
++++This unmanaged Index consists of long-term revenue bonds, prerefunded 
    bonds, general obligation bonds and insured bonds.



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