MUNICIPAL INVT TR FD MON PYMT SER 542 DEFINED ASSET FDS
S-6EL24, 1994-05-02
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     AS FILED WITH THE SECURITIES AND EXCHANGE COMMISSION ON MAY 2, 1994
                                        REGISTRATION NO. 33-
==============================================================================

                      SECURITIES AND EXCHANGE COMMISSION

                           WASHINGTON, D. C. 20549
                               _______________

                                   FORM S-6
                               _______________

                  FOR REGISTRATION UNDER THE SECURITIES ACT
                   OF 1933 OF SECURITIES OF UNIT INVESTMENT
                       TRUSTS REGISTERED ON FORM N-8B-2
                               _______________

A.  EXACT NAME OF TRUST:

                       MUNICIPAL INVESTMENT TRUST FUND
                          MONTHLY PAYMENT SERIES-542
                             DEFINED ASSET FUNDS

B.  NAMES OF DEPOSITORS:

              MERRILL LYNCH, PIERCE, FENNER & SMITH INCORPORATED
                          SMITH BARNEY SHEARSON INC.
                           PAINEWEBBER INCORPORATED
                      PRUDENTIAL SECURITIES INCORPORATED
                          DEAN WITTER REYNOLDS INC.

C.  COMPLETE ADDRESSES OF DEPOSITORS' PRINCIPAL EXECUTIVE OFFICES:

MERRILL LYNCH, PIERCE, FENNER & SMITH           SMITH BARNEY SHEARSON INC.
           INCORPORATED                           TWO WORLD TRADE CENTER
          P.O. BOX 9051                                 101ST FLOOR
    PRINCETON, N.J. 08543-9051                     NEW YORK, N.Y. 10048


 PAINEWEBBER INCORPORATED     PRUDENTIAL SECURITIES      DEAN WITTER REYNOLDS
1285 AVE. OF THE AMERICAS         INCORPORATED                   INC.
   NEW YORK, N.Y. 10019        ONE SEAPORT PLAZA      TWO WORLD TRADE CENTER--
                                199 WATER STREET             69TH FLOOR
                              NEW YORK, N.Y.  10292     NEW YORK, N.Y. 10048


D.  NAMES AND COMPLETE ADDRESSES OF AGENTS FOR SERVICE:

   TERESA KONCICK, ESQ.       THOMAS D. HARMAN, ESQ.         LEE B. SPENCER
       P.O BOX 9051            388 GREENWICH STREET         ONE SEAPORT PLAZA
PRINCETON, N.J. 08543-9051     NEW YORK, N.Y. 10013         199 WATER STREET
                                                          NEW YORK, N.Y. 10292

                                                           COPIES TO
   PHILIP BECKER           ROBERT E. HOLLEY       PIERRE DE SAINT PHALLE, ESQ.
 130 LIBERTY STREET--      1200 HARBOR BLVD.          450 LEXINGTON AVENUE
    29TH FLOOR           WEEHAWKEN, N.J. 07087        NEW YORK, N.Y. 10017
NEW YORK, N. Y. 10006

E.  TITLE AND AMOUNT OF SECURITIES BEING REGISTERED:

 An indefinite number of Units of Beneficial Interest pursuant to Rule 24f-2
      promulgated under the Investment Company Act of 1940, as amended.

F.  PROPOSED MAXIMUM OFFERING PRICE TO THE PUBLIC OF THE SECURITIES BEING
    REGISTERED:

                                  Indefinite

G.  AMOUNT OF FILING FEE:

                       $500 (as required by Rule 24f-2)

H.  APPROXIMATE DATE OF PROPOSED SALE TO THE PUBLIC:

 As soon as practicable after the acquisition and deposit of the underlying
obligations.

THE REGISTRANT HEREBY AMENDS THIS REGISTRATION STATEMENT ON SUCH DATE OR
DATES AS MAY BE NECESSARY TO DELAY ITS EFFECTIVE DATE UNTIL THE REGISTRANT
SHALL FILE A FURTHER AMENDMENT WHICH SPECIFICALLY STATES THAT THIS
REGISTRATION STATEMENT SHALL THEREAFTER BECOME EFFECTIVE IN ACCORDANCE WITH
SECTION 8(A)  OF THE SECURITIES ACT OF 1933 OR UNTIL THE REGISTRATION
STATEMENT SHALL BECOME EFFECTIVE ON SUCH DATE AS THE COMMISSION, ACTING
PURSUANT TO SAID SECTION 8(A), MAY DETERMINE.
==============================================================================


           SUBJECT TO COMPLETION, PROSPECTUS DATED MAY 2, 1994


==============================================================================
                                               MUNICIPAL INVESTMENT TRUST FUND
                                                    MONTHLY PAYMENT SERIES-542
20,000 UNITS                                               DEFINED ASSET FUNDS
==============================================================================

     A FINAL PROSPECTUS FOR A PRIOR MONTHLY PAYMENT SERIES OF MUNICIPAL
INVESTMENT TRUST FUND, DEFINED ASSET FUNDS IS HEREBY INCORPORATED BY
REFERENCE AND USED AS A PRELIMINARY PROSPECTUS FOR THIS MONTHLY PAYMENT
SERIES.  THE NARRATIVE INFORMATION AND STRUCTURE OF THE FINAL PROSPECTUS
FOR THIS SERIES WILL BE SUBSTANTIALLY THE SAME AS THAT OF THE PREVIOUS
PROSPECTUS.  INFORMATION WITH RESPECT TO PRICING, THE NUMBER OF UNITS,
DATES AND SUMMARY INFORMATION REGARDING THE CHARACTERISTICS OF SECURITIES
TO BE DEPOSITED IN THIS SERIES IS NOT NOW AVAILABLE AND WILL BE DIFFERENT
FROM THAT SHOWN SINCE EACH SERIES HAS A UNIQUE PORTFOLIO.  IN ADDITION,
CERTAIN NON-MATERIAL CHANGES MAY BE MADE TO THE DESCRIPTIONS OF THE TRUST
AGREEMENT FOR THIS SERIES TO REFLECT PROPOSED CHANGES TO THE TRUST
AGREEMENT.  ACCORDINGLY, THE INFORMATION CONTAINED HEREIN WITH REGARD TO
THE PREVIOUS SERIES SHOULD BE CONSIDERED AS BEING INCLUDED FOR
INFORMATIONAL PURPOSES ONLY.  RATINGS OF THE SECURITIES IN THIS SERIES ARE
EXPECTED TO BE COMPARABLE TO THOSE OF THE SECURITIES DEPOSITED IN THE
PREVIOUS SERIES.  HOWEVER, THE ESTIMATED CURRENT AND LONG-TERM RETURNS FOR
THIS SERIES WILL DEPEND ON THE INTEREST RATES AND OFFERING SIDE EVALUATIONS
OF THE SECURITIES IN THIS SERIES AND MAY VARY MATERIALLY FROM THAT OF THE
PREVIOUS SERIES.  INVESTORS SHOULD CONTACT ACCOUNT EXECUTIVES OF THE
UNDERWRITERS WHO WILL BE INFORMED OF THE EXPECTED EFFECTIVE DATE OF THIS
SERIES AND WHO WILL BE SUPPLIED WITH COMPLETE INFORMATION WITH RESPECT TO
SUCH SERIES ON THE DAY OF AND IMMEDIATELY PRIOR TO THE EFFECTIVENESS OF THE
REGISTRATION STATEMENT RELATING TO UNITS OF THIS SERIES.


     INFORMATION CONTAINED HEREIN IS SUBJECT TO COMPLETION OR AMENDMENT.  A
REGISTRATION STATEMENT RELATING TO THESE SECURITIES HAS BEEN FILED WITH THE
SECURITIES AND EXCHANGE COMMISSION.  THESE SECURITIES MAY NOT BE SOLD NOR
MAY OFFERS TO BUY BE ACCEPTED PRIOR TO THE TIME THE REGISTRATION STATEMENT
BECOMES EFFECTIVE.  THIS PROSPECTUS SHALL NOT CONSTITUTE AN OFFER TO SELL
OR THE SOLICITATION OF AN OFFER TO BUY NOR SHALL THERE BE ANY SALE OF THESE
SECURITIES IN ANY STATE IN WHICH SUCH OFFER, SOLICITATION OR SALE WOULD BE
UNLAWFUL PRIOR TO REGISTRATION OR QUALIFICATION UNDER THE SECURITIES LAWS
OF ANY SUCH STATE.


                                   PART II

            ADDITIONAL INFORMATION NOT INCLUDED IN THE PROSPECTUS

     A.  The following information relating to the Depositors is
incorporated by reference to the SEC filings indicated and made a part of
this Registration Statement.
                                                             SEC FILE OR
                                                          IDENTIFICATION NO.
                                                          __________________

I.   Bonding Arrangements and Date of Organization of the Depositors filed
     pursuant to Items A and B of Part II of the Registration Statement on
     Form S-6 under the Securities Act of 1933:

         Merrill Lynch, Pierce, Fenner & Smith Incorporated       2-52691
         Prudential Securities Incorporated                       2-61418
         Smith Barney Shearson Inc.                              33-29106
         Dean Witter Reynolds Inc.                                2-60599
         PaineWebber Incorporated                                 2-87965

II. Information as to Officers and Directors of the Depositors filed
    pursuant to Schedules A and D of Form BD under Rules 15b1-1 and 15b3-1
    of the Securities Exchange Act of 1934:

         Merrill Lynch, Pierce, Fenner & Smith Incorporated        8-7721
         Prudential Securities Incorporated                       8-12321
         Smith Barney Shearson Inc.                                8-8177
         Dean Witter Reynolds Inc.                                8-14172
         PaineWebber Incorporated                                 8-16267


III. Charter documents of the Depositors filed as Exhibits to the
     Registration Statement on Form S-6 under the Securities Act of 1933
     (Charter, By-Laws):

         Merrill Lynch, Pierce, Fenner & Smith
           Incorporated                                  2-73866, 2-77549
         Prudential Securities Incorporated              2-86941, 2-86941
         Smith Barney Shearson Inc.                              33-20499
         Dean Witter Reynolds Inc.                       2-60599, 2-86941
         PaineWebber Incorporated                        2-87965, 2-87965

     B.  The Internal Revenue Service Employer Identification Numbers of
the Sponsors and Trustee are as follows:
.\"the Sponsors and Co-Trustees are as follows:

         Merrill Lynch, Pierce, Fenner & Smith Incorporated    13-5674085
         Prudential Securities Incorporated                    13-6134767
         Smith Barney Shearson Inc.                            13-1912900
         Dean Witter Reynolds Inc.                             94-1671384
         PaineWebber Incorporated                              13-2638166
         Bankers Trust Company                                 13-4941297


                                     II-1


      Supplemented final prospectuses from the following Series of
Municipal Investment Trust Fund, Defined Asset Funds (all of which are
incorporated herein by reference) may be used as preliminary prospectuses
for this Monthly Payment Series - 533 (Reg. No. 33-50121); Monthly
Payment Series - 534 (Reg. No. 33-50493); Monthly Payment Series - 535
(Reg. No. 33-50765); Monthly Payment Series - 536 (Reg. No. 33-51197);
Monthly Payment Series - 537 (Reg. No. 33-51871). Monthly Payment Series
- - 538 (Reg. No. 33-52019); Monthly Payment Series - 539 (Reg. No. 33-
52179).

                      CONTENTS OF REGISTRATION STATEMENT

 THE REGISTRATION STATEMENT ON FORM S-6 COMPRISES THE FOLLOWING PAPERS AND
DOCUMENTS:

 The facing sheet of Form S-6.
 The Cross-Reference Sheet (incorporated by reference to the
   Cross-Reference Sheet to the Registration Statement of Municipal
   Investment Trust Fund, Three Hundred Tenth Monthly Payment Series,
   1933 Act File No. 2-88372).
 The Prospectus.
 Additional Information not included in the Prospectus (Part II).
 *Consent of independent public accountants.

 The following exhibits:

      1.1       --  Form of Trust Indenture (incorporated by reference to
                    Exhibit 1.1 to the Registration Statement of Municipal
                    Investment Trust Fund, Monthly Payment Series-533,
                    Defined Asset Funds, 1933 Act File No. 33-50121).

      1.1.1     --  Form of Standard Terms and Conditions of Trust Effective
                    October 21, 1993 (incorporated by reference to Exhibit
                    1.1.1 to the Registration Statement of Municipal
                    Investment Trust Fund, Multistate Series-48, Defined
                    Asset Funds, 1933 Act File No. 33-50247).

      1.2       --  Form of Master Agreement Among Underwriters (incorporated
                    by reference to Exhibit 1.2 to the Registration Statement
                    of The Corporate Income Fund, One Hundred Ninety-Fourth
                    Monthly Payment Series, 1933 Act File No. 2-90925).

      2.1       --  Form of Certificate of Beneficial Interest (included in
                    Exhibit 1.1.1).

     *3.1       --  Opinion of counsel as to the legality of the securities
                    being issued including their consent to the use of their
                    names under the headings "Taxes" and "Miscellaneous-
                    Legal Opinion" in the Prospectus.

     *4.1       --  Consent of the Evaluator.

__________

  * To be filed with Amendment to the Registration Statement.


                                     R-1


                                  SIGNATURES

     PURSUANT TO THE REQUIREMENTS OF THE SECURITIES ACT OF 1933, THE
REGISTRANT HAS DULY CAUSED THIS REGISTRATION STATEMENT OR AMENDMENT TO THE
REGISTRATION STATEMENT TO BE SIGNED ON ITS BEHALF BY THE UNDERSIGNED
THEREUNTO DULY AUTHORIZED IN THE CITY OF NEW YORK AND STATE OF NEW YORK ON
THE 2ND DAY OF MAY, 1994.


            Signatures appear on pages R-3, R-4, R-5, R-6 and R-7.

     A majority of the members of the Board of Directors of Merrill Lynch,
Pierce, Fenner & Smith Incorporated has signed this Registration Statement
or Amendment to the Registration Statement pursuant to Powers of Attorney
authorizing the person signing this Registration Statement or Amendment to
the Registration Statement to do so on behalf of such members.

     A majority of the members of the Executive Committee of the Board of
Directors of Prudential Securities Incorporated has signed this
Registration Statement or Amendment to the Registration Statement pursuant
to Powers of Attorney authorizing the person signing this Registration
Statement or Amendment to the Registration Statement to do so on behalf of
such members.

     A majority of the members of the Board of Directors of Smith Barney
Shearson Inc. has signed this Registration Statement or Amendment to the
Registration Statement pursuant to Powers of Attorney authorizing the
person signing this Registration Statement or Amendment to the Registration
Statement to do so on behalf of such members.

     A majority of the members of the Board of Directors of Dean Witter
Reynolds Inc. has signed this Registration Statement or Amendment to the
Registration Statement pursuant to Powers of Attorney authorizing the
person signing this Registration Statement or Amendment to the Registration
Statement to do so on behalf of such members.

     A majority of the members of the Executive Committee of the Board of
Directors of PaineWebber Incorporated has signed this Registration
Statement or Amendment to the Registration Statement pursuant to Powers of
Attorney authorizing the person signing this Registration Statement or
Amendment to the Registration Statement to do so on behalf of such members.


                                     R-2


MERRILL LYNCH, PIERCE, FENNER & SMITH INCORPORATED
               DEPOSITOR


By the following persons, who constitute a        Powers of Attorney have been
   majority of the Board of Directors of          filed under Form SE and
   Merrill Lynch, Pierce, Fenner & Smith          the following 1933 Act
   Incorporated:                                  File Number: 33-43466

       HERBERT M. ALLISON, JR.
       BARRY S. FRIEDBERG
       EDWARD L. GOLDBERG
       STEPHEN L. HAMMERMAN
       JEROME P. KENNEY
       DAVID H. KOMANSKY
       DANIEL T. NAPOLI
       THOMAS H. PATRICK
       JOHN L. STEFFENS
       DANIEL P. TULLY
       ROGER M. VASEY
       ARTHUR H. ZEIKEL








       By  ERNEST V. FABIO
          (As authorized signatory for
          Merrill Lynch, Pierce, Fenner & Smith Incorporated
          and Attorney-in-fact for the persons listed above)


                                     R-3


   PRUDENTIAL SECURITIES INCORPORATED
          DEPOSITOR


   By the following persons,                Powers of Attorney have been
      who constitute a majority of            filed under Form SE and
      the Executive Committee of              the following 1933 Act
      the Board of Directors of               File Number: 33-41631
      Prudential Securities Incorporated:


       JAMES T. GAHAN
       ALAN D. HOGAN
       HOWARD A. KNIGHT
       GEORGE A. MURRAY
       LELAND B. PATON
       HARDWICK SIMMONS




       By  RICHARD R. HOFFMANN
          (As authorized signatory for
          Prudential Securities Incorporated
          and Attorney-in-fact for the persons listed above)


                                     R-4


   SMITH BARNEY SHEARSON INC.
          DEPOSITOR


   By the following persons,                Powers of Attorney have
      who constitute a majority of             been filed under the
      the Board of Directors of                1933 Act File
      Smith Barney Shearson Inc.:              Numbers: 33-49753
                                               and 33-51607

       RONALD A. ARTINIAN
       STEVEN D. BLACK
       JAMES BOSHART III
       ROBERT A. CASE
       ROBERT K. DIFAZIO
       JAMES DIMON
       ROBERT DRUSKIN
       HERBERT DUNN
       TONI ELLIOTT
       LEWIS GLUCKSMAN
       ROBERT F. GREENHILL
       THOMAS GUBA
       HENRY U. HARRIS
       JOHN B. HOFFMAN
       A. RICHARD JANIAK, JR.
       ROBERT Q. JONES
       ROBERT B. KANE
       JEFFREY LANE
       JACK H. LEHMAN III
       ROBERT H. LESSIN
       JOEL N. LEVY
       THOMAS A. MAGUIRE, JR.
       JOHN J. McATEE, JR.
       HOWARD D. MARSH
       JOHN F. McCANN
       WILLIAM J. MILLS II
       JOHN C. MORRIS
       CHARLES O'CONNOR
       HUGH J. O'HARE
       JOSEPH J. PLUMERI II
       JACK L. RIVKIN
       A. GEORGE SAKS
       BRUCE D. SARGENT
       DON M. SHAGRIN
       DAVID M. STANDRIDGE
       MELVIN B. TAUB
       JACQUES S. THERIOT
       STEPHEN J. TREADWAY
       PAUL UNDERWOOD
       PHILIP M. WATERMAN


       By  GINA LEMON
          (As authorized signatory for
          Smith Barney Shearson Inc. and
          Attorney-in-fact for the persons listed above)


                                     R-5


   DEAN WITTER REYNOLDS INC.
          DEPOSITOR



   By the following persons,         Powers of Attorney have been
      who constitute a majority of     filed under Form SE and
      the Board of Directors of        the following 1933 Act
      Dean Witter Reynolds Inc.:       File Number: 33-17085

          NANCY DONOVAN
          CHARLES A. FIUMEFREDDO
          JAMES F. HIGGINS
          STEPHEN R. MILLER
          PHILIP J. PURCELL
          THOMAS C. SCHNEIDER
          WILLIAM B. SMITH




          By  MICHAEL D. BROWNE
             (As authorized signatory for
             Dean Witter Reynolds Inc. and
             Attorney-in-fact for the persons listed above)


                                     R-6


   PAINEWEBBER INCORPORATED
      DEPOSITOR



   By the following persons, who                Powers of Attorney have
      constitute a majority of the                been filed under
      Executive Committee of the                  Form SE and the
      Board of Directors of                       following 1933 Act
      PaineWebber Incorporated:                   File Number: 33-28452


              JOHN A. BULT
              PAUL B. GUENTHER
              DONALD B. MARRON
              RONALD M. SCHWARTZ
              JAMES C. TREADWAY


              By  ROBERT E. HOLLEY
                 (As authorized signatory for
                 PaineWebber Incorporated and
                 Attorney-in-fact for the persons listed above)


                                     R-7



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