MEMC ELECTRONIC MATERIALS INC
S-8, EX-5, 2000-08-10
SEMICONDUCTORS & RELATED DEVICES
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                                                                  Bryan Cave LLP
                                                        700 Thirteenth Street NW
                                                       Washington, DC 20005-3960
                                                                  (202) 508-6000
                                                      Facsimile:  (202) 508-6200

                                 August 10, 2000



MEMC Electronic Materials, Inc.
501 Pearl Drive (City of O'Fallon)
St. Peters, Missouri 63376

Ladies and Gentlemen:

     We have acted as special  counsel to MEMC Electronic  Materials,  Inc. (the
"Company") in connection with the  registration on Form S-8 under the Securities
Act of 1933,  as  amended,  by the Company of a total of  3,600,000  shares (the
"Shares") of the Company's common stock,  $.01 par value per share,  issuable by
the  Company  upon the  exercise of awards  granted  pursuant to the 1995 Equity
Incentive Plan, as amended and restated through August 3, 2000 (the "Plan").

     In connection  herewith,  we have examined and relied as to matters of fact
upon such certificates of public officials, such certificates of officers of the
Company and originals or copies  certified to our  satisfaction  of the Restated
Certificate  of  Incorporation  and Restated  Bylaws of the  Company,  the Plan,
proceedings  of the  Board of  Directors  of the  Company  and  other  corporate
records, documents,  certificates and instruments as we have deemed necessary or
appropriate in order to enable us to render the opinion expressed below.

     In rendering the following opinion,  we have assumed the genuineness of all
signatures on all documents  examined by us, the  authenticity  of all documents
submitted to us as originals and the  conformity  to authentic  originals of all
documents submitted to us as certified or photostatted  copies. In addition,  we
have  assumed  that the  certificates  for the Shares to be issued  will be duly
registered and countersigned by the Company's transfer agent.

     Based on the foregoing and in reliance thereon,  we are of the opinion that
the shares have been duly and validly  authorized for issuance and, when issued,
delivered and paid for in accordance  with the terms and conditions of the Plan,
will be validly issued, fully paid and non-assessable.

     We  hereby  consent  to the  filing  of this  opinion  as  Exhibit 5 to the
aforesaid registration statement on Form S-8.

                                         Sincerely,


                                         /s/ Bryan Cave LLP
                                         Bryan Cave LLP



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